Experiments

This page documents the outline of expected experiments to be conducted during the wet lab phase.

Experiments - Del Norte SD iGEM

Purpose

To build and test a synthetic AND logic gate system in E. Coli that detects two signs of skin inflammation, which are nitric oxide (NO) and hydrogen peroxide (H₂O₂), and activates downstream gene expression only when both signals are present.

Materials

Part Name
BBa_K1153000 NorV promoter. NOx detector.
BBa_K1216007 wild-type pLuxR promoter
BBa_C0062 luxR repressor/activator
BBa_C0062 LuxI
BBa_E0040 GFP
BBa_K4216007 pOxyS
BBa_B0015 double terminator
BBa_B0034 RBS (Elowitz)

Reagents:

  • IDT synthesized gene fragments (with EcoRI and PstI ends)
  • Plasmid backbones: puc19 and pJUMP-1A
  • Restriction enzymes: EcoRI, PstI (NEB)
  • 10X NEBuffer
  • Agarose, TAE buffer, Gel loading dye, DNA ladder
  • PCR Clean up kit
  • Gel extraction kit
  • ThermoScientific GeneJet Gel Extraction Kit
  • T4 DNA Ligase + Ligase buffer
  • Competent E. coli cells (TOP10)/NEB Stable competent cells
  • Antibiotics: Chloramphenicol (30 µg/mL), Kanamycin (50 µg/mL), Ampicillin, 50 µg/mL
  • Miniprep Kit
  • LB plates with specific antibiotics
  • LB broth
  • NO donor (DETA-NONOate)
  • H₂O₂ (starting at 50 uM)

Equipment:

  • Thermal cycler or water bath
  • Gel electrophoresis system
  • Incubator (37°C)
  • Shaking incubator
  • NanoDrop spectrophotometer
  • Centrifuge
  • Microcentrifuge tubes, pipettes
  • GFP-compatible plate reader or fluorimeter

Planned Lab Protocol

(More detailed versions in our lab notebook)

1. Design + Synthesis:

  1. Order custom inserts from IDT:

    • EcoRI + PnorV + RBS + LuxR + Terminator + PstI
    • EcoRI + PoxyS + RBS + Plux + GFP + Terminator + PSTI
  2. 2. Cloning & Assembly

  3. Digest Plasmid Backbones [puc19 & pJUMP-1A(sfGFP)] - NEB protocol (Total reaction volume 50 uL):

    • DNA (Plasmids and/or Inserts separately): 1 ug
    • 10X NEB buffer: 5 uL
    • EcoRI: 1 uL
    • PstI: 1 uL
    • Nuclease-free water: Up to 50 uL

    Mix reaction by pipetting, centrifuge briefly. Incubate at 37°C for 1 hour. Heat-inactivate at 65°C for 20 minutes.

    Analysis of Digest and Gel Purification - Run digested products on 1% agarose gel. Use gel extraction kit to purify plasmids and backbones.

    Ligation - Use a 1:3 vector to insert ratio. Make ligation mixture (20 uL Total Volume):

    • Vector: 50 ng each plasmid
    • Insert: 93 ng of the NO insert, 79 ng of the H₂O₂ insert
    • 10X ligase buffer: 2 uL or 2x quick ligation buffer 10 uL
    • T4 DNA Ligase: 1 uL
    • Water to 20 uL

    Mix components, incubate at 16°C overnight or 10 minutes at room temp. Include a vector-only negative control.

  4. 3. Transformation (Competent E. coli)

  5. Use E. coli TOP10. Thaw 50 uL of competent cells on ice, add 2-5 uL of DNA. Incubate on ice for 30 minutes. Heat shock at 42°C for 45 seconds, then return to ice for 2 minutes. Recover in LB (no antibiotics) with shaking at 37°C for 1 hour. Plate on LB + Ampicillin (30 µg/mL) for puc19 construct or Kanamycin (50 µg/mL) for pJUMP construct. Incubate at 37°C overnight.

  6. 4. Cloning Confirmation

  7. Plasmid miniprep + Digest - Grow colonies in 5 mL LB + respective antibiotic overnight. Perform plasmid miniprep. Digest minipreps with EcoRI + PstI and run on a 1% agarose gel to confirm insert size.

  8. 5. Confirmation of successful cloning

  9. Co-transform both plasmids into fresh E. coli TOP10. Plate on LB + Ampicillin + Kanamycin. Pick colonies and grow in 5 mL LB with both antibiotics overnight. Subculture 1:100 into fresh media. At mid-log phase (OD600 ~0.4–0.6), split into tubes for induction:

    • Control: no inducers
    • + NO donor: 100 µM DETA-NONOate
    • + H₂O₂: start at 50 µM, test range
    • + Both inducers

    Incubate 4–6 hrs at 37°C with shaking. Measure GFP fluorescence (Ex: ~488 nm, Em: ~510 nm), normalized to OD600.

  10. 6. Future Directions

  11. Replace GFP with therapeutic gene (iaaM+iaaH complex for indole-3-acetic acid synthesis). Re-characterize using the same protocol.

Controls and Design

To verify the function of our dual-sensor AND gate system, we designed both positive and negative controls. Negative control: E. coli transformed with only one plasmid (either the NO or H₂O₂ plasmid) and grown without inducers. This ensures that GFP expression does not occur in the absence of one or both signals. Additionally, E. coli cotransformed with both plasmids but with only one inducer added should not produce GFP either. We will test this as well.

Positive control: E. coli transformed with both plasmids and treated with both NO (DETA-NONOate) and H₂O₂ to activate the AND gate. This condition should produce the highest GFP fluorescence.

Replicates: Each condition will be performed in triples to ensure reproducibility and allow calculation of standard deviation.

This design confirms whether both signals are required for gene expression and helps validate the function of the regulatory elements (PnorV, PoxyS, Plux).

Engineering and Results

Our team followed the engineering design cycle—design, build, test, learn—in order to conduct our wet lab protocols. This page further documents our steps in the lab and how we iterated on the protocols for optimized results.

We conducted a series of validation steps to ensure that we were on the right track when performing the lab protocols. This page documents all results that were obtained from our experimentation.

Troubleshooting

During the cloning process, potential challenges included incomplete digestion, low PCR efficiency (likely due to machine errors), or ligation inefficiency. To address this, we planned to run all digests on a 1% agarose gel to confirm fragment sizes before ligation and use a 1:3 vector-to-insert ratio based on NEB’s ligation calculator to maximize success.

Improved steps:

  • PCR step didn’t yield high enough insert DNA concentration → re-do with longer elongation step and more cycles
  • Low insert DNA concentration after gel extraction → switch to PCR clean up
  • No colonies for initial choice of chloramphenicol resistance vector → switch to pUC19 instead, it has a more compatible origin of replication too with pJUMP-1A and decrease antibiotic concentration
  • Low concentration of pJUMP after vector-only transformation and miniprep → inoculate E. Coli again with the vector and grow for a longer period of time in a liquid culture before miniprepping
  • Low concentration of pJUMP post-restriction → inoculate E. Coli again with the vector, grow in SOC media and improve DNA yield
  • No colonies after post-ligation vectors were transformed → Re-do transformation, allow the bacteria incubate on ice for 30 minutes before the heat shock and let the transformed cells recover in SOC media for one hour before plating on selective media.
  • Sequencing showed incomplete digestion and ligation → optimize PCR for longer elongation time and more cycles, let the restriction digest incubate overnight at room temperature, ligate with higher insert:vector concentrations.

If transformation yields few colonies, we will check antibiotic concentrations, repeat with freshly prepared competent cells, and include a vector-only negative control to confirm background levels. To prevent recombination, we will grow in NEB Stable Competent cells. For fluorescence readings, if signal strength is low, we will verify that the cultures reached mid-log phase (OD₆₀₀ 0.4–0.6) before induction, as promoter activity depends on growth phase.

Outcome and Relevance

The expected outcome is that E. coli cotransformed with both plasmids will only express GFP when exposed to both nitric oxide and hydrogen peroxide, confirming proper AND gate behavior. This would demonstrate that the system can detect inflammatory signals and produce a measurable output.

Successful GFP expression will validate our design and cloning process, allowing us to later replace GFP with the therapeutic genes for indole-3-acetic acid synthesis. These results will inform the next engineering cycle by confirming promoter functionality, regulatory response, and compatibility between plasmids.

Note: Complete documentation of all lab protocols we used along with exact volumes and concentrations that we changed can be found in our lab notebook.

Next Steps

For our next engineering cycle, we plan to:

  • Repeat digestion with fresh restriction enzymes and extended incubation.
  • Research maximal optimized protocols for each step in the cloning protocol.
  • The PCR protocol will be improved through a longer elongation step and more cycles to improve insert concentration after performing gel extraction.
  • Use PCR cleanup exclusively for inserts.
  • Increase insert DNA concentration and ligation ratio.
  • Transform into NEB Stable cells and test with GFP with fluorescence assays to validate the predicted AND gate logic.
  • Measure different concentrations of inducers to create a dose-response curve and compare with our Hill’s equation model.
  • Conduct research into safe and optimal concentrations of IAA to use in our plasmid system such that the final product will be both safe to apply on the skin and effective in reducing inflammation.
  • Replace GFP with indole-3-acetic acid complex (iaaM and iaaH genes) and test inducer and output concentrations both in-vitro and in-vivo.